This example started at a workshop at ICERM about thinking about K3 surfaces on the LMFDB.
It is the $ψ=-1/4$ fiber of the pencil $F_1L_3$, which has generic rank 19, thus $\operatorname{rank}\operatorname{Pic}X^{al} \geq 19$.
Matching upper bounds can be deduced by positive characteristic methods: Lectures 1 and 2 give $\operatorname{rank}\operatorname{Pic}X^{al} \leq 19$.
The pencil has a symplectic $\mathbf{Z}/7\mathbf{Z}$ action. Its coinvariant lattice $\Omega_7=(H^2(X,\mathbf{Z})^{\mathbf{Z}/7\mathbf{Z}})^\perp$ has rank $18$ and determinant $7^3$.
$\operatorname{Pic}(X^{al})=\langle4\rangle\oplus\Omega_7$, of determinant $4\cdot7^3=1372$ and saturation index $1$.